博士，百人计划青年杰出人才，副教授，硕士生导师

邮箱:zhxt@gzhu.edu.cn

电话：18529122363

 

教育经历

2012–2017香港大学 物理化学 理论与计算化学 理学博士 导师：David Lee Phillips 教授

2010–2012中山大学 物理化学 理论与计算化学 理学硕士 导师：赵存元教授

2003–2007广东工业大学 环境工程 工学本科

 

工作经历

2021年12月至今，化学与化工学院黄埔氢能源创新中心副教授

2017-2021香港大学David Lee Phillips 教授组副研究员

 

研究方向

主要综合Gaussian、ORCA、Material Studio、VASP、Multiwfn等量子化学计算和分析软件，以国际上广泛使用的密度泛函（DFT）方法为主，研究1）氢能源电池电极催化反应机理；2）金属配合物光电催化；3）小分子光化学等，以及4）更高效的催化剂的理论设计与筛选。 

 

主持项目

 Funding scheme: Seed Fund for Basic Research (HK$: 106,560)，01/02/2021-31/01/2022，主持

 

代表性论文

[1] F. Wei; S. Kuang; T. W. Rees; X. Liao; J. Liu; D. Luo; J. Wang^*; Xiting Zhang^*; L. Ji; H. Chao^*. Ruthenium(II) Complexes Coordinated to Graphitic Carbon Nitride: Oxygen Self-Sufficient Photosensitizers Which Produce Multiple ROS for Photodynamic Therapy in Hypoxia. Biomaterials. 276 (2021) 121064. ( 通讯作者, IF: 12.479) 

[2] C. Ouyang; Y. Li; T. W. Rees; X. Liao; J. Jia; Y. Chen^*; Xiting Zhang^*; L. Ji; H. Chao^*. Supramolecular Assembly of an Organoplatinum(II) Complex with Ratiometric Dual Emission for Two-Photon Bioimaging. Angewandte Chemie International Edition. 60(8),4150-4157,2021. (通讯作者, IF: 12.257)

[3] S. Kuang; L. Sun; X. Zhang; X. Liao; T. W. Rees; L. Zeng; Y. Chen^*; Xiting Zhang^*; L. Ji; H. Chao^*. A Mitochondrion-Localized Two-Photon Photosensitizer Generating Carbon Radicals against Hypoxic Tumors. Angewandte Chemie International Edition. 59(46), 20697-20703, 2020. (通讯作者, IF: 12.257)

[4] J. Ma^*,§; Xiting Zhang^*,§; N. Basaric; D. L. Phillips^*. Direct Observation of Photoinduced Ultrafast Generation of Singlet and Triplet Quinone Methides in Aqueous Solutions and Insight into the Roles of Acidic and Basic Sites in Quinone Methide Formation. Journal of the American Chemical Society. 139，18349-18357，2017. (通 讯+同等一作, IF: 14.695)

[5]Xiting Zhang; J. Ma^*; D. L. Phillips^*. To Photoredox or Not in Neutral Aqueous Solutions for Selected Benzophenone and Anthraquinone Derivatives. Journal of Physical Chemistry Letters. 7, 4860–4864, 2016. (第一作者，IF: 7.329)

[6]Xiting Zhang^§; Y. Guo^§; E. Dallin; J. Ma^*; M. Dai; D. L. Phillips^*. An Unusual Acetonitrile Adduct Formed via Photolysis of 4'-Chloro-2-Hydroxybiphenyl in Aqueous Solution. Journal of Organic Chemistry. 85, 11635–11640, 2020. (第一作者，IF: 4.335).

[7]Xiting Zhang; J. Ma^*; S. Li; M. Li; X. Guan; R. Zhu; D. L. Phillips^*. Ketyl Radical Formation via Proton-Coupled Electron Transfer in Aqueous Solution versus Hydrogen Atom Transfer in Isopropanol After Photoexcitation of Aromatic Carbonyl Compounds. Journal of Organic Chemistry. 81, 5330–5336, 2016. (第一作者，IF: 4.335)

[8]Xiting Zhang; Z. Ke; N. J. DeYonker; H. Xu; Z.-F. Li; X. Xu; X. Zhang; C.-Y. Su^*; D. L. Phillips; C. Zhao^*. Mechanism and Enantioselectivity of Dirhodium-Catalyzed Intramolecular C–H Amination of Sulfamate. Journal of Organic Chemistry. 78, 12460–12468, 2013. (第一作者，IF: 4.335)

[9] J. Zhao^§; Xiting Zhang^§; R. Zhu; T. Su; D. L. Phillips^*. Photophysical Properties Controlled by Substituents with Lone-Pair Electrons at the Ortho- or Para-Positions of Fluoroquinolone Antibiotics. Journal of Physical Chemistry: B. 123, 3156-3162, 2019. (同等一作，IF: 2.923)

 

其他论文

[10] J. Ma^*; Xiting Zhang; D. L. Phillips^*. Time-Resolved Spectroscopic Observation and Characterization of Water-Assisted Photoredox Reactions of Selected Aromatic Carbonyl Compounds. Accounts of Chemical Research. 52, 3, 726-737, 2019. (第二作者，IF: 21.661)

[11] Q. Song^§; Xiting Zhang^§; J. Ma^*; D. L. Phillips^*. Time-Resolved Spectroscopic Study on the Photoredox Reaction of 2-(p-Hydroxymethyl)phenyl Anthraquinone. Scientific Reports. 7, 9154, 2017. (同等一作，IF：4.011)

[12] Y. Li; Xiting Zhang; Z. Yan; L. Du^*; W. Tang^*; D. L. Phillips^*. Photochemical α-Cleavage Reaction of 3′,5′-Dimethoxybenzoin: A Combined Time-Resolved Spectroscopy and Computational Chemistry Study. Molecules. 25(15), 3548, 2020.

[13] L. Du; Xiting Zhang; J. Xue; W. Tang; M.-D. Li; X. Lan; J. Zhu; R. Zhu; Y. Weng; Y.-L. Li^*; D. L. Phillips^*. The Influence of Water in the Photogeneration and Properties of a Bifunctional Quinone Methide. Journal of Physical Chemistry: B. 120, 11132–11141, 2016.

[14] J. Ma; Xiting Zhang; N. Basarić; P. Wan; D. L. Phillips^*. Observation of Excited State Proton Transfer Reactions in 2-Phenylphenol and 2-Phenyl-1-naphthol and Formation of QuinoneMethide Species. Physical Chemistry Chemical Physics. 17, 9205-9211, 2015.

[15] H. Xu; Xiting Zhang; Z.-F. Ke; Z.-F. Li; X.-Y. Xu; C.-Y. Su; D. L. Phillips^*; C. Zhao^*. Density Functional Theory Study of the Mechanism of Zinc Carbenoid Promoted Cyclopropanation of Allenamides. RSC Advances. 3, 17131-17142, 2013.

[16] Z. Li^*; Xiting Zhang; H. Li; Y. Zhu; X. Yang. Theoretical Observations of π-Systems as Sodium Bond Donors. Chemical Physics Letters. 510, 273-277, 2011.

[17] J. Zhao; R. Zhu; Xiting Zhang; B. Zhang; Y. Liu; Y. Li; W. Wang^*; D. L. Phillips^*. Photoenhanced Oxidation of Amino Acids and the Cross-Linking of Lysozyme Mediated by Tetrazolium Salts. Physical Chemistry Chemical Physics. 23, 3761-3770, 2021.

[18] J. Ma^*; H. Li; Xiting Zhang; M. Li; D. L. Phillips^*. Competition Between “Meta-Effect” Photochemical Reactions of Selected Benzophenone Compounds Having Two Different Substituents at Meta Positions. Journal of Organic Chemistry. 81, 9553-9559, 2016.

[19] J. Wei; L. Wu; H.-X. Wang; Xiting Zhang; C.-W. Tse; C.-Y. Zhou; J.-S. Huang; C.-M. Che^*. Iron-Catalyzed Highly Enantioselective cis-Dihydroxylation of Trisubstituted Alkenes with Aqueous H₂O₂.Angewandte Chemie International Edition. 59(38), 16561-16571, 2020.

[20] L. Du; M.-D. Li; Y. Zhang; J. Xue; Xiting Zhang; R. Zhu; S. C. Cheng; X. Li; D. L. Phillips^*. Photoconversion of beta-Lapachone to alpha-Lapachone via a Protonation Assisted Singlet Excited State Pathway in Aqueous Solution: A Time-Resolved Spectroscopic Study. Journal of Organic Chemistry. 80, 7340-7350, 2015.

[21] J. Huang; J. Ma^*; M. Li; M. Liu; Xiting Zhang; D. L. Phillips^*. How does the C-Halogen Bond Break in the Photosubstitution Reaction of 3-Fluorobenzophenone in Acidic Aqueous Solutions. Journal of Organic Chemistry. 80, 9425-9436, 2015.

[22] X. Zhang; X. Xu; H. Xu; Xiting Zhang; D. L. Phillips; C. Zhao^*. Mechanistic Investigation into the Cleavage of a Phosphomonoester Mediated by a Symmetrical Oxyimine-Based Macrocyclic Zinc(II) Complex. ChemPhysChem. 15, 1887–1898, 2014.

[23] J. Ma; T. Su; M.-D. Li; Xiting Zhang; J. Huang; D. L. Phillips^*. Meta versus Para Substitution: How Does C-H Activation in a Methyl Group Occur in 3-Methylbenzophenone But Does Not Take Place in 4-Methylbenzophenone. Journal of Organic Chemistry. 78, 4867-4878, 2013.

[24] H. Wang; N. J. DeYonker; Xiting Zhang; C. Zhao^*; L. Ji; Z-W Mao^*. Photodissociation of a Ruthenium(II) Arene Complex and its Subsequent Interactions With Biomolecules: A Density Functional Theory Study. Journal of Molecular Modeling. 18, 4675-4686, 2012.

[25] Z.-F. Li; Y. Fan; N. J. DeYonker; Xiting Zhang; C.-Y. Su; H. Xu; X. Xu; C. Zhao^*. Platinum(II)-Catalyzed Cyclization Sequence of Aryl Alkynes via C(sp³)-H Activation: A DFT Study. Journal of Organic Chemistry. 77, 6076-6086, 2012.

[26] H. Wang; N. J. DeYonker; H. Gao; C. Tan; Xiting Zhang; L. Ji; C. Zhao^*; Z.-W. Mao^*. Aquation and Dimerization of Osmium(II) Anticancer Complexes: A Density Functional Theory Study. RSC Advances. 2, 436-446, 2012.